Catalytic Depolymerization of Alkali Lignin in Sub- and Super-critical Ethanol
نویسندگان
چکیده
منابع مشابه
Catalytic Depolymerization of Alkali Lignin in Sub- and Super-critical Ethanol
The effects of reaction parameters on catalytic depolymerization of alkali lignin in suband super-critical ethanol were investigated using a high pressure autoclave, and the liquid oil and solid char products were characterized. The experimental data indicated that Rh catalysis, controlling reaction conditions at ethanol critical temperature (240 oC) and pressure (7.0 MPa), high ethanol/water r...
متن کاملCatalytic Depolymerization of Lignin and Woody Biomass in Supercritical Ethanol: Influence of Reaction Temperature and Feedstock
The one-step ethanolysis approach to upgrade lignin to monomeric aromatics using a CuMgAl mixed oxide catalyst is studied in detail. The influence of reaction temperature (200-420 °C) on the product distribution is investigated. At low temperature (200-250 °C), recondensation is dominant, while char-forming reactions become significant at high reaction temperature (>380 °C). At preferred interm...
متن کاملPhenolics Production through Catalytic Depolymerization of Alkali Lignin with Metal Chlorides
Lignin is an important renewable source of phenolic products. In this study, alkali lignin was depolymerized to produce phenolic compounds. The effects of catalyst, solvent, reaction time, and reaction temperature on the yields of liquid products and volatile fractions were investigated in detail. Compared with the solvents water and octane, alcohols can significantly promote depolymerization o...
متن کاملCatalytic Oxidation and Depolymerization of Lignin in Aqueous Ionic Liquid
Lignin is an integral part of the plant cell wall, which provides rigidity to plants, also contributes to the recalcitrance of the lignocellulosic biomass to biochemical and biological deconstruction. Lignin is a promising renewable feedstock for aromatic chemicals; however, an efficient and economic lignin depolymerization method needs to be developed to enable the conversion. In this study, w...
متن کاملLow-Power Microwave Radiation-assisted Depolymerization of Ethanol Organosolv Lignin in Ethanol/Formic Acid Mixtures
Ethanol organosolv lignin separated from bamboo was depolymerized by low-power microwave radiation (~80 W) using ethanol as a swelling agent and formic acid as a hydrogen donor solvent. After increasing the temperature from 100 to 200 °C, the total amount of phenolic compounds in the products increased from 8.1% to 40.8%, and both the weight average molecular weight (Mw) and number average mole...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: BioResources
سال: 2017
ISSN: 1930-2126
DOI: 10.15376/biores.12.3.5001-5016